She stated "Right. Someone like him" in chapter 7-1 (~7:25) after she stated she likes them tall and blonde. I don't think she's made any other references about her feelings towards Angel other than "Angel keeps trying, but I don't think he gets it." 15-1 (~9:40).
Statistically, 1 out of every 10 people in the United States is identified as a member of the LGBT community. There are 25 people in the Tower. Stands to reason one or two of them might be homosexual.
I think not considering the possibility Riley is a lesbian is just nuts.
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